Sustainable Development Goals
Abstract/Objectives
In this proposal, we plan to develop sustainable green energy technologies which combine a high-energy-density and high-safety energy storage system (lithium-ion batteries (LIBs) and sodium-ion batteries (NIBs)) with a green power generation system (microbial fuel cells (MFCs) and plant microbial fuel cells (PMFCs)). The objective of this proposal in the field of LIBs and NIBs is to develop novel electrode materials (biowaste-derived carbon materials, polyoxometalates, metal-organic-framework, and high-entropy oxides) and solid electrolyte materials (oxide-based electrolytes) which are able to satisfy the demands of energy storage with high energy density, high safety, long cycling life, and low cost. The charge storage mechanism of electrodes and charge transfer mechanism of electrolytes will be carefully studied through several in-situ techniques as well as DFT calculations. The other important objective is to develop biowaste-derived carbon electrode materials for MFCs and PMFCs in order to meet the strategies of circular economy for sustainable energy.
Results/Contributions

This project has successfully developed various electrode materials for lithium-ion batteries and sodium-ion batteries, such as novel polyoxometalates, high-entropy ceramics, Prussian blue analogs, 2D materials, and agricultural-waste- derived porous carbon materials, etc. They all exhibit excellent capacity, fast charge and discharge performance, and long cycle life. In addition, the in-situ X-ray absorption spectroscopy, X-ray diffractometer and penetrating X-ray microscope in National Synchrotron Radiation Center are used to study the energy storage mechanism of those electrode materials during charging and discharging processes. Among them, waste-coffee-ground-derived porous carbon anode material provided high cycle stability and excellent rate performance. In addition to the advantages of low cost and reduced environmental pollution, its good battery performance can be applied to the large-scale energy storage market.

This project also utilizes porous carbon materials derived from waste coffee grounds and water chestnut shells as anode materials for MFCs and PMFCs. This agricultural-waste-derived carbon materials exhibit good conductivity, porosity and biocompatibility, which enables facile biofilm formation on the surface, effectively reduces the electron transfer resistance, and increases the power density. In addition, those MFCs and PMFCs exhibit long-term stability. The above results show that the application of carbon materials derived from agricultural wastes to MFCs and PMFCs has the advantages of high power and low cost.

Keywords
Lithium ion batteries, sodium ion batteries energy storagemicrobial fuel cellsplant microbial fuel cells
Contact Information
陳翰儀副教授
hanyi.chen@mx.nthu.edu.tw